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(last updated 5 Jun 2007)
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Congress has been asked to order an independent study of whether toxic phosgene gas left in depleted uranium cylinders poses a danger at the Paducah Gaseous Diffusion Plant.
A House-Senate conference committee approved the study on Monday night (Nov. 7, 2005).
Sen. Mitch McConnell, R-Ky., inserted the study order in the final spending bill for energy and water programs and projects, which was approved by the conference committee. McConnell was a member of the committee.
The measure is expected to pass the House and Senate this week and be sent to President Bush.
(Courier Journal Nov. 9, 2005)
The report, released on June 15, 2006, cannot rule out the possibility of phosgene still being present in depleted uranium hexafluoride cylinders:
"This report documents work aimed at determining whether phosgene (COCl2) could survive the chemical environment of a UF6 cylinder from the time of filling with liquid UF6 many years ago to the present day.Investigation of the Chemical Reactivity of Phosgene in Uranium Hexafluoride
Information was obtained from the scientific literature, from thermodynamic calculations, and from limited laboratory experimentation. The conclusion derived from this work is that COCl2 is more resistant to chemical reaction than expected. We have demonstrated that at least a portion could survive the short-term contact with liquid UF6 during cylinder filling. We cannot say from the information developed whether it could survive the long-term contact at lower temperature."
On May 31, 2007, the U.S. Government Accountability Office released a report finding that DOE's phosgene characterization study was flawed because investigators did not document parts of the work. The report also said some U.S. Department of Energy employees reviewing the study may have had a conflict of interest because they took part in the initial inspection. (Herald Leader June 4, 2007)
United States Government Accountability Office: DOE's Investigation of Phosgene Gas Contamination Was Inadequate, but Experts Conclude That Worker Safety and Facilities Are Not Threatened
, May 2007 (PDF)
Demonstration of jackhammer incorporating depleted uranium, by Fischer, L E; Hoard, R W; Carter, D L; Saculla, M D; Wilson, G V; U.S. Department of Energy, Lawrence Livermore National Laboratory, Report No. UCRL-ID-138923, April 1, 2000, 18p
> Download full report
(2M PDF, LLNL)
As a consequence, the report proposes to perform risk estimates of the new DU uses, to justify - if found to be "acceptable" - adding new exemptions or general licenses to the NRC regulations. In the end, this would allow for dispersal of DU in radiologically uncontrolled areas.
Regulation of new depleted uranium uses, by N. L. Ranek, U.S. DOE Report No. ANL/EAD/TM/02-5, Jan. 2003, 52 p.
> Download full report (OSTI)
· alternate source (DOE EAD)
(160k PDF)
In a further report, DOE provides "guidance on the process for petitioning the U.S. Nuclear Regulatory Commission (NRC) to initiate a rulemaking that could reduce the licensing burden for new products containing depleted uranium (DU) [...] The focus is on requirements of the NRC rulemaking process applicable to establishing new exemptions or general licenses for products and devices containing source material. [...] The report recommends that the U.S. Department of Energy formulate a regulatory plan for deployment of DU-containing products in areas that are not already radiologically controlled. Such a plan is needed because deployment of new DU-containing products may be difficult under existing NRC licensing requirements. " (emphasis added):
A Process for Reducing the Licensing Burden for New Products Containing Depleted Uranium, by N. L. Ranek, S. Kamboj, H. M. Hartmann, H. Avci, Environmental Assessment Division, Argonne National Laboratory, ANL/EAD/TM/03-01, Nov. 2003, 56 p.
> Download full report (OSTI)
· alternate source (DOE EAD)
(1MB PDF)
"ERP No. F-DOE-E09014-KY Paducah, Kentucky, Site Depleted Uranium Hexafluoride Conversion Facility, Construction and Operation, McCraken County, KY.Federal Register: August 6, 2004 (Volume 69, Number 151) p. 47927 (download full text
Summary: EPA continues to express concern since radiological monitoring, appropriate storage and disposition of radioactive waste will be necessary during the operation phase."
"concluded that the Department's plan for converting depleted uranium hexafluoride inventories could be improved by adding an additional conversion line to the Portsmouth facility. Currently, plans call for three conversion lines, which will be capable of processing 13,500 metric tons of depleted uranium hexafluoride per year. By adding another conversion line, Portsmouth could process 4,500 metric tons of additional material annually and complete the project nearly 5 years earlier than planned. The facility size was not optimized because the Department's acquisition strategy emphasized initial capital costs rather than minimizing life-cycle costs. By increasing the production capacity at Portsmouth, the Department could shorten the duration of the Portsmouth conversion project by about 5 years and save about $55 million."
Audit Report, Depleted Uranium Hexafluoride Conversion, U.S. Department of Energy, Office of Inspector General, Office of Audit Services, DOE/IG-0642, March 2004
> Download IG report
(2M PDF)
"ERP No. D-DOE-F09004-OH Rating EC2, Portsmouth, Ohio Site Depleted Uranium Hexafluoride Conversion Facility, Construction and Operation, Pike County, OH.
Summary: EPA has environmental concerns over the measurement units and proper reference to NESHAP standards, and the cumulative effects of the new enrichment facility that will be built on the site."
Federal Register: February 20, 2004 (Volume 69, Number 34) p. 7942
(download full text
)
Comments had to be submitted by February 2, 2004.
> View DOE release April 29, 2003 ![]()
> Download Transportation Plan for the Transport of ANSI N14.1-Compliant UF6 Cylinders from the East Tennessee Technology Park to the Portsmouth Gaseous Diffusion Plant in Years 2003 through 2005, BJC/OR-1432 , April 2003
(2.7MB PDF)
"[...] In light of Public Law 107-206, and DOE's award of the contract to Uranium Disposition Services, DOE reevaluated the appropriate scope of its NEPA review and decided to prepare two separate EIS's, one for the plant proposed for the Paducah site and a second for the Portsmouth site. The proposed alternatives to be considered in each EIS would focus primarily on where the conversion facilities will be sited at the respective sites, and a no action alternative. DOE will also consider impacts arising from shipment of ETTP cylinders for conversion to each site."
> View DOE Release Oct. 30, 2001 ![]()
> View Federal Register Notice, Sep 18, 2001 ![]()
> See also Federal Register Notice, May 7, 2001
Background documents (DOE EAD):
> View DOE release Oct. 31, 2000 ![]()
> Download Request for Proposals
"The U.S. Department of Energy (DOE) today issued a solicitation seeking private sector solutions for converting tons of depleted uranium hexafluoride stored at government facilities in Kentucky, Ohio, and Tennessee to a safer form. The solicitation for 'Expressions of Interest,' asks private industry to submit innovative strategies for transforming the 700,000 metric tons of depleted uranium hexafluoride (DUF6) to a safer, more environmentally benign state. The DOE is seeking ideas from industry to help it construct the conversion plants at Paducah, Kentucky and Portsmouth, Ohio, well before the construction deadline of January 31, 2004." (DOE News Release March 5, 1999> View the complete solicitation of Expressions of Interest)
> Download DOE's Final Plan for the Conversion of Depleted Uranium Hexafluoride
, July 1999 (362k PDF format).
> View related DOE press release of July 6, 1999
> View DOE's Preconceptual Design Studies and Cost Data of Depleted Uranium Hexafluoride Conversion Plants
(July 26, 1999).
On March 23, 2000, DOE announced a deferral of the plans for construction of the conversion facilities, to allow for an assesmment of the possible presence of transuranics such as plutonium and neptunium in its DU stockpile.
(DOE release March 23, 2000
)
Federal Register: April 3, 2007 (Volume 72, Number 63) p. 15869-15871 (download full text
)
> Download Supplement Analysis: Depleted UF6 Management Information Network
or DOE NEPA
Haire, M.J. and R.R. Price 2001. "Technical Review of Depleted Uranium Uses Research and Development Program," Office of Environmental Management, Washington, DC USA, U.S. Department of Energy, 01/16/2001.
> Download full presentation
(1.9MB PDF)
excerpt:
"Task JustificationA first UO3 Schottky diode has been fabricated.
- Semiconductor devices that are based on uranium oxides appear possible and could offer significant improved performance compared to conventional Si, Ge, and GaAs materials
- If depleted uranium (DU) were used instead of silicon for semiconductive devices, 42,000 t/y of DU would be consumed. Approximately 20,000 t/y of DU is produced each year as tails from uranium enrichment operations
- Objective is to develop order of magnitudes improvements, new markets, and consume entire DU inventory"
For technical details, see also:
Uranium Oxide Semiconductors
(DOE ANL EAD)
Comments on the draft Roadmap will be accepted during a public comment period that ends on October 20, 2000.
> View Federal Register Notice, September 7, 2000
U.S. Department of Energy: Draft DUF6 Materials Use Roadmap, September 1, 2000
> Download full text
(2.8M PDF)
> Download Draft - Nevada Test and Training Range Depleted Uranium Target Disposal Environmental Assessment, United States Air Force Air Combat Command, Sep. 2004
(2.7M PDF) - expires Oct. 25, 2004
> Download Nevada's comments on the draft EA, Oct. 19, 2004
(PDF)
Assessment of Preferred Depleted Uranium Disposal Forms, by A. G. Croff, J. R. Hightower, D. W. Lee, et al., Chemical Technology Division, OAK RIDGE NATIONAL LABORATORY, U.S. DEPARTMENT OF ENERGY, ORNL/TM-2000/161, June 2000, 24 p.
> download ORNL study(125k PDF)
(from NMI News Release, May 5, 1997) Nuclear Metals, Inc., a
Concord, Massachusetts based advanced metals technology company,
has today announced the receipt of its first contract to
demonstrate production of several tons of depleted uranium (DU)
aggregate. This aggregate (Trade-named DUCRETE
), when
combined with cement, will be used to produce low cost radiation
shielding for nuclear waste applications.
[Nuclear Metals later was renamed Starmet Corp.
]
On August 2, 1999, Energy Secretary Bill Richardson signed the Record of Decision for the Long-Term Management and Use of DUF6.
> Download DUF6 ROD
(59k PDF format)
> View related notice in Federal Register: August 10, 1999 (Vol. 64, No. 153)
p. 43358-43364 (download full text
).
On April 22, 1999, U.S. DOE released the
Final Programmatic Environmental Impact Statement for Alternative Strategies for the Long-Term Management and Use of Depleted Uranium Hexafluoride, U.S. Department of Energy, DOE/EIS-0269, April 1999> View Notice of availability (Federal Register April 29, 1999)
The PEIS assesses the potential environmental impacts of alternative strategies for the long-term management and use of 739,000 metric tonnes of depleted uranium hexafluoride (UF6) currently stored in cylinders at the three gaseous diffusion plant sites located near Paducah, Kentucky; Portsmouth, Ohio; and Oak Ridge, Tennessee.
Compared to the Draft PEIS, the preferred alternative has been revised to begin conversion of the UF6 to safer chemical forms as soon as possible, independent of the identification of potential uses of the material.
Excerpts from the Final PEIS Executive Summary:
"DOE's preferred alternative is to begin conversion of the UF6 inventory as soon as possible, either to uranium oxide, uranium metal, or a combination of both, while allowing for use of as much of this inventory as possible. Conversion to oxide for use or long-term storage would begin as soon as practicable, with conversion to metal occurring only if uses are identified. The preferred alternative would allow beneficial use of the material with regard to environmental, economic, technical, and other factors." [...]"Large-scale uses for the depleted uranium products are under development. These uses include radiation-shielding applications, in which uranium oxide is used as a substitute for the aggregate in concrete. Concrete made with depleted uranium would be a more effective shielding material than conventional concrete and would provide the same level of radiation shielding with less thickness than conventional concrete. Among other uses, this concrete could be fabricated into casks for storage of spent nuclear fuel or HLW.
In addition to the above potential large-scale uses of the depleted UF6, small-scale use of some depleted UF6 is being considered in industrial applications and by other DOE program decisions and NEPA analyses, such as that for the disposition of surplus plutonium." [...]
For details, see Depleted Uranium Hexafluoride Programmatic Environmental Impact Statement
(U.S. DOE Argonne National Laboratory - Environmental Assessment Division)
In addition, the full text of the following reports is available for download from LLNL Documents On-Line
:
> View IEER comments on the draft PEIS (March 1998)
> View What's Ahead for the Nation's Depleted Uranium Hexafluoride?
by Mary Byrd Davis, Yggdrasil Institute (May 1999)
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